Journal of Alloys and Compounds2022,Vol.8988.DOI:10.1016/j.jallcom.2021.162993

(162993)Intense cold-white emission due to native defects in Zn_2GeO_4 nanocrystals

Jaime Dolado Javier Garcia-Fernandez Pedro Hidalgo
Journal of Alloys and Compounds2022,Vol.8988.DOI:10.1016/j.jallcom.2021.162993

(162993)Intense cold-white emission due to native defects in Zn_2GeO_4 nanocrystals

Jaime Dolado 1Javier Garcia-Fernandez 2Pedro Hidalgo1
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作者信息

  • 1. University Complutense of Madrid, Department of Materials Physics, Madrid 28040, Spain
  • 2. Universidad Complutense of Madrid, Department of Inorganic Chemistry, Madrid 28040, Spain
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Abstract

Broad emission bands in semiconducting oxides due to native defects could readily be an efficient source of white light if they are adjusted properly. In this work, Zn_2GeO_4 nanoparticles of 10 and 16 nm sizes, obtained by a precipitation method, are presented as potential white light emitter. Temperature dependence measurements have been performed to discuss the Zn_2GeO_4 luminescence, which consist of emission bands in the ultraviolet, blue and green regions. The analysis of these results provided some clues about the interplay between defect-related centres and the surface states in nanocrystalline Zn_2GeO_4. Finally, a highly efficient cold-white emission at room temperature has been achieved from this nanomaterial.

Key words

White emission/Photoluminescence/Native defects/Zinc germanate/Nanocrystals

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出版年

2022
Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
被引量3
参考文献量44
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