首页|Ethenolysis of methyl oleate in room-temperature ionic liquids
Ethenolysis of methyl oleate in room-temperature ionic liquids
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NSTL
Wiley
Unsaturated vegetable oils are an attractive renewable feedstock, and the selective cleavage of unsaturated fatty esters is an important transformation in this respect. The efficient and selective cross-metathesis of methyl oleate with ethylene was achieved under mild conditions with ruthenium-alkylidene catalysts in toluene and room-temperature ionic liquids (RTILs) to give two important chemical intermediates, 1-decene and methyl 9-decenoate, without double-bond migration. As recovery of the catalyst is on important target with respect to industrial applications, catalyst recycling studies were also carried out in RTILs with the first-generation Hoveyda catalyst.
NSTL
Wiley
