Abstract
In this paper, the impact of CO2-carbonate interactions on hydrocarbon recovery from three initially oil-saturated heterogeneous carbonate core samples (with low and mid permeabilities) were investigated. Alternate injection of carbon dioxide (CO2) and synthetic formation brine was conducted after water flooding. X-ray computed tomography scanning of the core samples before and after core flooding was performed at ambient conditions. Extent of carbonate dissolutions and rock matrix modifications were observed from the change in porosities, permeabilities, and wormhole formations. Generally, the CO2-WAG injection resulted in more than 30% extra oil recovery from the three cores after water flooding scenario. As expected, the total recovery factor of the core with lowest initial permeability and porosity was the smallest, however the core permeability increased from 1.45 mD (pre-flood) to 1987.9 mD (post-flood). Considerable amount of oil was left behind in the core with initially low permeability and porosity due to preferentially flow of WAG fluid through the wormholes, bypassing the trapped oil in the pore spaces at the uninvaded region of the rock. The study suggests that low oil recovery from core with low initial permeability and porosity is principally due to formation of wormhole because of rapid rate of rock dissolution and faster rate of CO2-carbonate reactions. Compared to the mid permeability cores, the low permeable core slows down the WAG fluid flow and give more time for CO2-carbonate rock interactions and reactions because of the tightness of the pore spaces. Thus, facilitated more exposure time and effective contact between the carbonate rock fabrics and the CO2-saturated brine.
NSTL
Elsevier