首页|Isomer engineering of universal electron transport materials for suppressed exciton quenching in organic light-emitting diodes
Isomer engineering of universal electron transport materials for suppressed exciton quenching in organic light-emitting diodes
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NSTL
Elsevier
A regioisomer of 2,7-bis(4,6-diphenyl-1,3,5-triazin-2-yl)-9,9' -spirobi[fluorene] (m-SBFTrz), 3,6-bis(4,6-diphenyl-1,3,5-triazin-2-yl)-9,9' -spirobi[fluorene] (p-SBFTrz) was developed as a high triplet energy electron transport material by engineering the substitution position of diphenyltriazine to the spirobifluorene core. The p-SBFTrz showed great potential as an electron transport and exciton blocking materials in various devices such as thermally activated delayed fluorescence organic light-emitting diodes (OLEDs) and phosphorescence OLEDs due to increased triplet energy. A large improvement of the external quantum efficiency was achieved using the p-SBFTrz instead of m-SBFTrz by completely suppressing exciton quenching.
Spirobifluorene coreElectron transport materialHole blocking materialHigh triplet energySPIROBIFLUORENE DERIVATIVESIMPEDANCE SPECTROSCOPYMOBILITYDEVICESGREENHOST
NSTL
Elsevier
