首页|Two are better than one-Synthesis of novel blue and green emissive hydroxy-oxadiazoles
Two are better than one-Synthesis of novel blue and green emissive hydroxy-oxadiazoles
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We describe herein synthesis of novel hydroxy-bis-2,5-disubstituted-l,3,4-oxadiazoles and their ability to emit green light, through ESIPT mechanism. Unlike previous reports, our compounds exhibit very good quantum yields, most likely avoiding the presumed intramolecular fluorescence quenching in presence of the second oxadiazole moiety. Studies regarding behaviour of the compounds in polar and non-polar solvents are also described, indicating the possibility to modulate the emission according to the environment. The solid-state structural analysis, corroborated with fluorescence data, suggest the importance of the tert-butyl group in preservation of the luminescent properties. The corresponding benzyl-protected compounds, precursors to the target hydroxy-bis-2,5-disubstituted-l,3,4-oxadiazoles were also investigated for their optical properties and found to display very intense blue emission, with quantum yields values in dichloromethane (between 0.423 and 0.499) almost equal to the standard quinine sulfate.
University of Bucharest, Faculty of Chemistry, Department of Organic Chemistry, Biochemistry and Catalysis, Research Centre of Applied Organic Chemistry, 90-92 Panduri Street, RO-050663, Bucharest, Romania
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