首页|N-doped carbon coated porous hierarchical MnO microspheres as superior additive-free anode materials for lithium-ion batteries
N-doped carbon coated porous hierarchical MnO microspheres as superior additive-free anode materials for lithium-ion batteries
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NSTL
Elsevier
? 2021Novel N-doped carbon coated porous hierarchical MnO microspheres have been successfully synthesized via the simultaneous pyrolysis of MnCO3 and polyacrylonitrile (PAN) at low calcination temperature. The micro/nano structure with uniform N-doped carbon coating, suitable interior pores and tiny primary MnO nanocrystals can significantly increase the electronic conductivity of the composite, reduce the amount of irreversible solid-electrolyte interphase (SEI) layer, accommodate the huge volume change of MnO during cycling and facilitate easier redox reaction of Mn2+/Mnx+ (x>2) to generate extra capacity. By using partially pyrolytic PAN as the conductive agent and binder, the obtained additive-free MnO-based electrode (MnO@NC-S) demonstrates a high reversible capacity of 998 mAh g?1 after 100 cycles at 0.1 A g?1 and remarkable long-term cycling stability with the capacity of 629 mAh g?1 after 500 cycles at 0.5 A g?1.
NSTL
Elsevier
