首页|Molecular engineering of the fused azacycle donors in the D-A-π-A metal-free organic dyes for efficient dye-sensitized solar cells
Molecular engineering of the fused azacycle donors in the D-A-π-A metal-free organic dyes for efficient dye-sensitized solar cells
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Four novel D-A-7t-A metal-free organic sensitizers QL1-4 with the fused azacycle units as donors have been designed and synthesized to investigate the relationship between both the sizes and conjugations of azacycle and performances of dye-sensitized solar cells systematically. QL1 with the five-membered azacycle, i.e., with carbazole (Cz) as donor, exhibits the smallest molar extinction coefficients (e). QL2 and QL3 with the seven-membered azacycle, i.e. with N-phenyl-iminostilbene (ISB) and JV-phenyl-iminodibenzyl (IDB) as donors, respectively, show the red-shifted absorption spectra and higher e compared to QL1. However, QL2 and QL3 with an only distinction in a single or double bond, display distinctive PCEs. QL4 with the six-membered azacycle, i.e., 9,9,10-triphenyl-9,10-dihydroacridine (TDD), exhibits a blue-shifted absorption spectrum due to a big dihedral angle, resulting in a lower photovoltaic performance. Especially, QL3 with the ISB donor is conducive to achieving a PCE of 6.22%, which is higher than QL2, due to its better planar structure and more conjugation. When co-adsorbed with CDCA, QL3 exhibits the highest PCE of 7.14% among all dyes, and up to 8.26% by co-sensitizing with dye WL5, which surpasses that of the reference dye N719 (7.75%). The results indicate that the size and conjugation of the fused azacycle donors may affect the photovoltaic performance significantly, and the ISB unit is demonstrated as a promising donor for efficient organic dyes.
Dye-sensitized solar cellsAzacycleDonorOrganic dyeIminodibenzylIminostilbene
Ke Cai、Hanlun Wu、Tao Hua
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State Key Laboratory of Luminescent Materials and Devices, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, 510641, China
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