Photochemical a-deracemization of carbonyl compounds
Zhou, Yutong 1Ye, Juntao1
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作者信息
1. Shanghai Jiao Tong Univ
折叠
Abstract
Carbonyl compounds with a tertiary stereocenter at the a-position are an important class of building blocks in organic synthesis. However, efficient and enantioselective synthesis of this type of compounds are nontrivial. Photochemical deracemization reactions have emerged as a powerful tool towards this end. In this Digest, three recent studies are highlighted to demonstrate the great potential of this strategy and stimulate further development in this area. (C) 2022 Elsevier Ltd. All rights reserved.
Key words
Deracemization/Photocatalysis/Enantioselective synthesis/Carbonyl compounds/ENANTIOMERICALLY PURE ALCOHOLS/ENANTIOSELECTIVE PROTONATION/DYNAMIC RESOLUTION/ENERGY-TRANSFER/KETONES/DERACEMISATION
NSTL
Elsevier