首页|Self-supporting copper electrode prepared by ultrasonic impact for hydrogen evolution reaction

Self-supporting copper electrode prepared by ultrasonic impact for hydrogen evolution reaction

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Water electrolysis for hydrogen production requires highly active and inexpensive catalysts. Herein, we combine ultrasonic impact nanocrystallization (UIN) technology with nital etching method to rapidly prepare highly efficient self-supporting Cu electrode with abundant low-angle grain boundaries. When used as a catalyst for hydrogen evolution reaction (HER), the as-prepared electrode exhibits an overpotential of 353 mV at a current density of 10 mA cm-2, which is about 200 mV lower than that of the blank Cu plate. Moreover, the overpotential decreased to 246 mV after the stability test of 100 h, indicating a self-optimizing property. This work paves a new way for the preparation of self-supporting electrode with high performance.

Ultrasonic impactSelf-supporting electrodeHERDislocationCopperIN-SITUSTRAINELECTROCATALYSTSDISLOCATIONSCU(111)OXYGENSTM

Cheng, Mei-Yue、Cheng, Chuan-Qi、Feng, Yi、Fu, Le-Qi、Zhang, Fei-Fei、Yang, Tian-Tian、Li, Zhe、Ruan, Yi-Chen、Yang, Zhen-Wen、Lin, Kui、Liu, Hui、Du, Xi-Wen

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Tianjin Univ

2022

Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
年,卷(期):2022.916
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