首页|Li10Sn0.95P2S11.9?xOx: A new sulfide solid electrolyte for all-solid-state batteries
Li10Sn0.95P2S11.9?xOx: A new sulfide solid electrolyte for all-solid-state batteries
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NSTL
Elsevier
? 2022 Elsevier B.V.All-solid-state batteries (ASSBs) have high safety and high energy density. Li10SnP2S12 sulfide solid electrolyte has attracted extensive attention due to its low fabrication cost and outstanding performance in ASSBs. However, its ionic conductivity and stability to lithium and air need to be further improved. Here, in order to avoid the formation of impurities related to Sn-related compounds, the content of SnS2 in the raw materials is reduced, and to improve ionic conductivity and stability to lithium and air. The S site is doped with O by the solid-phase sintering method, and a series of Li10Sn0.95P2S11.9?xOx (0 ≤x ≤ 1) electrolytes are prepared. Li10Sn0.95P2S11.4O0.5 (LS0.95PSO0.5) has a high ionic conductivity of 3.96 mS cm?1 and low activation energy after cold pressing. According to the Hard-Soft-Acid-Base theory, doping O into the electrolyte in advance will improve the stability. The ionic conductivity decay of LS0.95PSO0.5 after exposure to air is smaller, which proves that O doping improves the air stability of the electrolyte. LS0.95PSO0.5 also shows good stability to lithium. The assembled LNO@LCO/LS0.95PSO0.5/Li-In ASSB exhibits a high first-cycle discharge capacity of 133 mA h g?1 and good cycling stability.
Key Laboratory of Eco-functional Polymer Materials of the Ministry of Education Key Laboratory of Eco-environmental Polymer Materials of Gansu Province College of Chemistry and Chemical Engineering Northwest Normal University
NSTL
Elsevier
