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New insight in photocatalytic degradation of textile dyes over CeO2/Ce2S3 composite

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Cerium oxide, sulfide and composites of cerium sulfide-cerium oxide were prepared by co-precipitation technique. The fabricated samples were characterized by XRD. The photocatalytic degradation of synthesized samples was made to check their catalytic performance. The results of photocatalytic activity verified that 94% degradation of the rhodamine B dye took place in presence of catalyst (composite of cerium oxide/sulfide) and UV-visible irradiation, whereas in catalyst absence, percentage degradation of rhodamine B dye was less than 15% at the end of 120 min. The composite of cerium oxide/sulfide showed greater photo degradation (94%) with rhodamine B dye under UV irradiation than cerium oxide (80%) and cerium sulfide (71%). Percentage degradation of composite materials was greater due to the band gap because photo catalysis depends upon the band gap energy. Band gap energy for composite of cerium oxide/sulfide may be calculated by Tauc relationship. Photo degradation reaction obeyed the rules of pseudo-first-order kinetic reaction.

Co-precipitationXRDPhotocatalytic degradationIrradiationLOW-TEMPERATURETHIN-FILMSNANOCOMPOSITESNANOSTRUCTURENANOPARTICLESCONVERSIONDESIGNROUTELIGHT

Rauf, Hibba-tu、Yasmin, Nazia、Ali, Ghulam、Ashiq, Muhammad Naeem、Safdar, Muhammad、Mirza, Misbah

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Women Univ Multan

Natl Univ Sci & Technol NUST

Bahauddin Zakariya Univ

Khawaja Fareed Univ Engn & Informat Technol

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2022

Physica

Physica

ISSN:0921-4526
年,卷(期):2022.632
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