首页|High-performance Zn-ion hybrid supercapacitor enabled by the hierarchical N/S co-doped graphene/polyaniline cathode
High-performance Zn-ion hybrid supercapacitor enabled by the hierarchical N/S co-doped graphene/polyaniline cathode
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NSTL
Elsevier
? 2022 Elsevier B.V.Zinc ion hybrid supercapacitors (Zn-HSCs), combined with the superiorities of supercapacitors and batteries, are regarded to have evolutive potential in devices of energy storage. Herein, the nitrogen and sulfur co-doped graphene/polyaniline nanoarrays (NSG/PANI) have been successfully compounded by in-situ polymerization. The structural characterization shows that the NSG/PANI-50 nanocomposite possess more active sites and vertically arranged PANI nanoarrays on the surface of NSG. The Zn-HSCs devices assembled by the zinc foil as anode, NSG/PANI-x (x = 30, 50, 70) as cathode and ZnSO4 as electrolyte (NSG/PANI//ZnSO4 (aq.)//Zn) show extraordinary energy storage properties. The prepared NSG/PANI-50//Zn device exhibits exceptional specific capacitance of 268.4 F g?1 at 0.1 A g?1 (the retention rate is 75.2% as the current density increased 20-times from 0.1 A g?1 to 2 A g?1), high energy density (95.4 Wh kg?1) and excellent capacitance retention rate of ~ 93% at 5 A g?1 after 10,000 cycles. The diffusion-controlled behavior (72% of the total storage charge at 5 mV s?1) suggests that the diffusion-controlled process acts a momentous role in the process of energy storage. The impressive results demonstrate that NSG/PANI nanocomposite could be a potential high-performance electrode material for Zn-ion hybrid energy systems.
High energy densityMetal anodeNSG/PANI nanocompositeNSG/PANI//ZnSO4 (aq.)//ZnZinc-ion hybrid supercapacitor
Song T.、Hao H.、Zhao Y.、Wang X.、Li C.、Li W.
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School of Materials Engineering Shanghai University of Engineering Science
NSTL
Elsevier
