首页|Enhanced light-to-thermal conversion performance of all-carbon aerogels based form-stable phase change material composites
Enhanced light-to-thermal conversion performance of all-carbon aerogels based form-stable phase change material composites
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NSTL
Elsevier
The exploitation of excellent performance form-stable phase change material composites (FS-PCMCs) with enhanced photothermal conversion efficiency and high phase change latent heat is of great significance for thermal energy storage. In this work, a new type of FS-PCMCs with superior light-to-thermal conversion performance were created by impregnation of organic phase change material (1-hexadecylamine (HDA) and 1-tetradecylamine (TDA)) into the graphene aerogel (GA) and all-carbon aerogel (GCA) through a simple direct infusion. The multiwalled carbon nanotubes (MWCNTs) are wound around the inner wall of the GA layer to form a three-dimensional (3D) porous network structure to support fatty amine (FAs), thus achieving shape stability before and after phase transition. Moreover, the FSPCMCs has extremely high phase transition enthalpy (203.1-248 kJ.kg(-1)) and good recyclability. More importantly, due to the high absorbance of GCA, it can enhance its light absorption capacity and reduce thermal radiation. The light-to-thermal conversion efficiency of the FS-PCMCs is 72.36%-88.25%. Taking the improvement of the comprehensive properties of the FS-PCMCs, the results of this work may open up a way for rational design and preparation of high-performance FS-PCMCs with enhanced storage capacity and light-to-thermal conversion efficiency for the efficient utilization of solar energy. (C) 2021 Elsevier Inc. All rights reserved.
Fatty amineAll-carbon aerogelLight-to-thermalPhase change materialThermal energy storageSOLAR-ENERGY CONVERSIONGRAPHENE OXIDEHEAT-TRANSFERCONDUCTIVITYSTORAGEBIOMASSMICROCAPSULESNANOCOMPOSITENANOTUBESADDITIVES
NSTL
Elsevier
