首页|Pd-modified TMU-3 metal-organic framework through a simple ion-exchange method as an efficient and reusable nanocatalyst for Sonogashira coupling reaction
Pd-modified TMU-3 metal-organic framework through a simple ion-exchange method as an efficient and reusable nanocatalyst for Sonogashira coupling reaction
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NSTL
Elsevier
In this paper, TMU-3 with the general formula [HDMA](2)[Zn-2(BDC)(3)(DMA)(2)] 6DMF as a type of metal-organic framework materials (MOFs) was employed as a support for palladium nanoparticles to preparation a reusable heterogeneous catalyst with high performance (Pd@TMU-3). The Pd@TMU-3 catalyst was synthesized through a simple impregnation procedure and ion exchange of cations HDMA(+) and Pd2+ in the TMU-3 and then was characterized by FT-IR, XRD, BET, FE-SEM, ESD-MAP, TGA, TEM, and ICP-OES. Based on the results, Pd@TMU-3 with 1.3 moll% loading of Pd exhibited excellent efficiency in the Sonogashira coupling reaction between phenylacetylene and aryl halides with both electron-donor and electron-acceptor groups, and the products were produced good to excellent yields. The heterogeneous nanocatalyst can be a promising candidate in green chemistry due to its high catalytic performance in a short reaction time, high purity of products, recoverability, facile preparation, and easy transfer, which can notably decrease the costs as well as possible pollutions. (C) 2022 Published by Elsevier B.V.
NSTL
Elsevier
