首页|A facile one-pot synth15esis of ionic liquid@porous organic frameworks for rapid high-capacity removal of heavy metal ions, pesticides and aflatoxin from two non-food bioactive products
A facile one-pot synth15esis of ionic liquid@porous organic frameworks for rapid high-capacity removal of heavy metal ions, pesticides and aflatoxin from two non-food bioactive products
扫码查看
点击上方二维码区域，可以放大扫码查看
原文链接
NSTL
Elsevier
Without inert gas protection and extra assistance by energy field, a green, facile, and catalyst-free strategy to synthesize ionic liquid@porous organic frameworks (IL@POFs) with high efficiency was developed for the first time. Besides, they have high specific surface area, stability and sustainability. As the brutal facts, many industrial crops are easily polluted and then cause safety risks. Among above IL@POFs, 1-butyl-3-methylimidazofium proline salt@porous organic framework ([C(4)mim][L-pro]@POF) exhibits rapid removal performance for typical heavy metal ions from Poria cocos (removing 100% Pb2+ within 5 min; 207.47 mg/g for Pb2+ and 62.85 mg/g for Cu2+). The separation mechanisms are coordination, accompanied by ion exchange and electrostatic interaction. Moreover, 1-butyl-3-methylimidazolium hexafluorophosphate@porous organic framework ([C(4)mim][PF6]@POF) could remove 85% triazophos and 93% aflatoxin B-1 (AFB(1)) effectively from Radices trichosanthis within 5 min, and multiple intermolecular interactions contribute to its adsorption capacity and selectivity. Above sorbents can be reused after effective elution. The proposed strategy not only provides valuable reference for the high-efficient synthesis of IL@POFs but also opens up a new pathway to recycling contaminated industrial crops.
NSTL
Elsevier
