首页|Ternary cobalt–iron–manganese layered double hydroxides with 1D/2D hierarchical nanostructure for oxygen evolution reaction and urea oxidation reaction
Ternary cobalt–iron–manganese layered double hydroxides with 1D/2D hierarchical nanostructure for oxygen evolution reaction and urea oxidation reaction
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NSTL
Elsevier
? 2022 Elsevier B.V.Developing high-efficient and stable electrocatalysts for oxygen evolution reaction (OER) is crucial for water splitting and metal-air batteries. Herein, ternary CoFe1?XMnX (0 <X < 1) layered double hydroxides (LDHs) grown on nickel form (NF) with nanosheet-nanowires (1D/2D) hierarchical nanostructure are synthesized. The introduction of Mn causes the change of crystal phase, morphology, and electronic structure of CoFe-LDH through electron transfer from Co/Fe to Mn, which provides the whole merit structural features and synergistic effect. Further experimental results exhibit that CoFe0.75Mn0.25-LDH possesses superior OER performance, which only requires overpotentials of 243 and 298 mV to reach 20 and 100 mA cm?2. The remodeling of LDHs in the OER process is also discussed to further explore the OER catalytic mechanism. In addition, CoFe0.75Mn0.25-LDH can also be utilized to the urea oxidation reaction (UOR), which requests a low potential of 1.367 V to reach 10 mA cm?2. A solar driven water splitting system is assembled and acquires the current density of 10 mA cm?2 at the low cell voltage of 1.58 V. This work offers an effective approach to boost the OER and UOR performance of CoFe-LDH based bifunctional electrocatalysts.
NSTL
Elsevier
