首页|Palladium nanoparticles decorated MXene for plasmon-enhanced photocatalysis

Palladium nanoparticles decorated MXene for plasmon-enhanced photocatalysis

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  • NSTL
  • Elsevier
? 2022 The Korean Society of Industrial and Engineering ChemistryTwo-dimensional MXene nanomaterials have found a wide application range in recent years. Here, Ti3C2 MXene nanosheets exhibiting inherent photothermal activity reveal synergistic plasmon-enhanced photocatalytic properties upon rational surface decoration with palladium nanoparticles (NPs). Pd incorporation induces a 1.7-fold increase in the number of defect sites on the MXene surface. Most importantly, the introduced Pd nanoparticles favour an effective separation and collection of localized surface plasmon resonance (LSPR)-induced hot charge carriers generated at the surface of semi-metallic Ti3C2 NS, further facilitating the generation of hydrogen peroxide (H2O2). The generated H2O2 is sequentially decomposed to hydroxyl radicals via the peroxidase (POD)-like activity of Pd NPs. The Pd@MXene shows approximately 2-fold enhancement of photocatalytic activity and excellent photostability under laser irradiation. Taken together, this study highlights the promise of constructing active and stable MXene-based nanohybrids for highly effective photo-responsive nanomedicine.

MXene nanosheetsNanozymePd nanoparticlesPeroxidase-like activity

Kim M.、Marques Mota F.、Kim D.H.、Jang D.、Hong H.、Yuan H.、Yu S.

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Department of Chemistry and Nano Science Ewha Womans University

Department of Biomicrosystem Technology

Department of Chemical Engineering and Materials Science College of Engineering Ewha Womans University

2022

10.1016/j.jiec.2022.01.030

Journal of industrial and engineering chemistry

Journal of industrial and engineering chemistry

EISCI
ISSN：1226-086X
年,卷(期)：2022.108
  • 9
  • 42