首页| Metal ion (Ca~(2+), Mg~(2+), Zn~(2+)) catalyzed synthesis of high-quality zeolite templated carbon

Metal ion (Ca~(2+), Mg~(2+), Zn~(2+)) catalyzed synthesis of high-quality zeolite templated carbon

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Three metal ions (Ca~(2+), Mg~(2+), and Zn~(2+)) were found to be successful catalysts to produce high-quality zeolite templated carbon (ZTC), a periodic three-dimensional graphene-like carbon with ordered microporous structure. Their roles in high-quality ZTC formation were studied by characterizing chemical component, surface morphology, structure, and pore properties. Ca~(2+), Mg~(2+), and Zn~(2+) minimize or eliminate the blockage of channels by carbon deposits and non-selective thermal deposition on the external surface of the zeolite particles. The growth temperature was lowered to only 450 °C. Moreover, the formation mechanism of ordered ZTC structure was revealed for the first time.

Carbon schwarziteZeolite templated carbonChemical vapor depositionMicroporousStructure ordering

Guangwu Yang、Liangbin Li、Hao Liu

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School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao, 266580, PR China

2022

Microporous and mesoporous materials

Microporous and mesoporous materials

EISCI
ISSN:1387-1811
年,卷(期):2022.336
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