首页|Thermal cycling behavior and failure mechanism of the Si-HfO2 environmental barrier coating bond coats prepared by atmospheric plasma spraying
Thermal cycling behavior and failure mechanism of the Si-HfO2 environmental barrier coating bond coats prepared by atmospheric plasma spraying
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NSTL
Elsevier
? 2022 Elsevier B.V.In this study, HfO2-doped Si bond coats with four different compositions were fabricated on the SiC substrates by atmospheric plasma spray (APS) for environmental barrier coating bond coats. The result showed that relatively dense composite bond coats can be successfully deposited by the APS approach using reduced plasma power to avoid the formation of metastable hafnia phases and hafnium silicides. The thermal expansion behavior of the Si-HfO2 bond coat was investigated. Results indicated that plasma-sprayed Si-HfO2 bond coats showed a non-linear expansion in air environment due to the oxidation of Si and formation of HfSiO4. Thermal cycling behavior of the Si-HfO2 bond coat at 1300 ℃ was also studied. The result suggested that the Si-HfO2 bond coat with high Si concentration has relatively better thermal shock resistance, owing to its low CTE and better oxidation resistance. The HfSiO4 formation reaction between hafnia and silica alleviate the volume contraction caused by cristobalite phase transformation. The spallation of the bond coat was attributed to the formation of thermally grown oxides (TGO) and the coefficient of thermal expansion (CTE) mismatch between the bond coat and the SiC substrate.
NSTL
Elsevier
