首页|High energy storage property of Na0.5Bi0.5TiO3-based ceramics modified by complex-ion and SrTiO3
High energy storage property of Na0.5Bi0.5TiO3-based ceramics modified by complex-ion and SrTiO3
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Elsevier
? 2022 Elsevier B.V.Exploring high-effect and pollution-free energy storage devices is the most important issue to be solved for many researchers. In this work, (Bi0.5Na0.5)TiO3-based lead-free ceramics were modified by La3+ in the A-site and (Al0.5Nb0.5)4+ in the B-site, respectively. In order to further modify, a linear dielectric of SrTiO3 was incorporated. By this means, novel (1-x)(Bi0.48La0.02Na0.5)Ti0.92 (Al0.5Nb0.5)0.08O3-xSrTiO3 [(1-x)(BLNANT)-xST] ceramics were prepared by traditional solid state reaction method. The crystal structure, microstructure, dielectric properties and energy storage properties were investigated. In particular, a great recoverable energy density (3.35 J/cm3) and efficiency (78.8%) were achieved under a low electric field of 255 kV/cm for the optimal composition. In addition, the P-E loops of this ceramic possess a good temperature (25–150 °C) and frequency stability (1–100 Hz) under the electric field of 150 kV/cm. Finally, an extremely fast discharge time (t0.9) of 71.3 ns and an eminent power density (PD) of 39.04 MW/cm3 can be obtained. These characteristics indicate that the ceramics of this work possess a good potential for high energy storage application.
Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials School of Materials Science and Engineering Shaanxi University of Science and Technology