首页|Nanofibers of solid-solution thorium(IV)-uranium(IV) oxides by electrospinning

Nanofibers of solid-solution thorium(IV)-uranium(IV) oxides by electrospinning

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Thorium-uranium dioxide nanofibers were prepared in a three-step process. Green composite microfibers were electrospun from solutions composed of Th(IV) and U(VI) acetylacetonate complexes in different molar ratios, polyvinylpyrrolidone, and acetone/ethanol mixed solvents. The second step converted the green composite fibers by calcination in the air to mixed Th/U oxide fibers. In the final step, the heat treatment under forming gas provided the nanofibers with diameters of 28 -46 nm composed of solid solutions ThxU1-xO2 ( x = 1, 0.75, 0.5, 0.25, 0). The XRD and STEM-EDS analyses of the prepared Th/U mixed oxide nanofibers attested to their atomic homogeneity. (C) 2022 Elsevier B.V. All rights reserved.

ElectrospinningThoriumUraniumMixed oxideNanofibersPolyvinylpyrrolidonePOLYMER NANOFIBERSSPARK PLASMAFUELSUO2

Kundrat, Vojtech、Vykoukal, Vit、Moravec, Zdenek、Pinkas, Jiri

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Masaryk Univ

2022

Journal of Nuclear Materials

Journal of Nuclear Materials

EISCI
ISSN:0022-3115
年,卷(期):2022.566
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