首页|(163148)Binary sulfuric effect on ZnO laminated carbon nanofibers hybrid structure for ultrafast lithium storage capability
(163148)Binary sulfuric effect on ZnO laminated carbon nanofibers hybrid structure for ultrafast lithium storage capability
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NSTL
Elsevier
The hybrid structure of high conductive carbon materials with large capacitive metal compounds is one of promising strategies for achieving high specific capacity, cycling stability, and ultrafast Li-ion storage capability due to their synergistic effects. This article will demonstrate the novel hybrid structure of a zinc oxysulflde (ZnOS) lamination layer on a sulfur (S)-doped carbon nanofiber (SCNF) matrix via an electro-spinning method with sequential atomic layer deposition (ALD) process and will also present the structural advantages for ultrafast Li-ion batteries (LIBs). As a double-anion material, ZnOS has benefits compared with single ZnO and ZnS during the charge/discharge process, which is accompanied with consecutive conversion and alloying reactions. To verify these factors, structural analysis at the atomic scale and various electrochemical properties were evaluated. The resultant ZnOS/SCNF electrode showed superior electrochemical performance such as high specific capacity (672.8 mAh g~(-1) at 100 mA g~(-1)), good capacity retention (87.8% after 100 cycles), and excellent cycling stability (85.4% after 500 cycles). This is attributed to the facilitated kinetic properties including electron and ion transfer efficiency during the electrochemical reactions, accompanied with the ZnOS/SCNF hybrid structure. In this regards, we believe that the ZnOS/SCNF electrode could be a great reference as a promising research strategy for accomplishing ultrafast LIBs.