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<![CDATA[CO <ce:inf loc="post">2</ce:inf> sequestration using red gypsum via pH-swing process: Effect of carbonation temperature and NH <ce:inf loc="post">4</ce:inf>HCO <ce:inf loc="post">3</ce:inf> on the process efficiency]]>

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<![CDATA[<ce:abstract xmlns:ce="http://www.elsevier.com/xml/common/dtd" xmlns="http://www.elsevier.com/xml/ja/dtd" id="ab0005" xml:lang="en" view="all" class="author"><ce:section-title id="st0005">Abstract</ce:section-title><ce:abstract-sec id="as0005" view="all"><ce:simple-para id="sp0055" view="all">The main purpose of this study is to investigate the effect of reaction temperature and NH<ce:inf loc="post">4</ce:inf>HCO<ce:inf loc="post">3</ce:inf>on the overall performance of a pH swing mineral carbonation. The overall performance of the pH swing process is investigated in terms of carbonation efficiency and product purity. Initially, 2M H<ce:inf loc="post">2</ce:inf>SO<ce:inf loc="post">4</ce:inf>is used for red gypsum dissolution at 70°C. Then in the second stage, NH<ce:inf loc="post">4</ce:inf>OH is added for increasing the solution pH and removing the impurities from solutions. Finally, CO<ce:inf loc="post">3</ce:inf><ce:sup loc="post">2–</ce:sup>is introduced to calcium rich solution in the form of pure CO<ce:inf loc="post">2</ce:inf>and NH<ce:inf loc="post">4</ce:inf>HCO<ce:inf loc="post">3</ce:inf>. The experimental results show that using NH<ce:inf loc="post">4</ce:inf>HCO<ce:inf loc="post">3</ce:inf>improves carbonation efficiency and product purity. Carbonation efficiency attains a maximum value at 75°C and then decreases gradually with increasing temperature up to 300°C, with both CO<ce:inf loc="post">2</ce:inf>and NH<ce:inf loc="post">4</ce:inf>HCO<ce:inf loc="post">3</ce:inf>. In this research, CaCO<ce:inf loc="post">3</ce:inf>with the maximum purity of 99.05% is produced successfully when NH<ce:inf loc="post">4</ce:inf>HCO<ce:inf loc="post">3</ce:inf>is used as a CO<ce:inf loc="post">3</ce:inf><ce:sup loc="post">2–</ce:sup>source.</ce:simple-para></ce:abstract-sec></ce:abstract><ce:abstract xmlns:ce="http://www.elsevier.com/xml/common/dtd" xmlns="http://www.elsevier.com/xml/ja/dtd" id="ab0010" class="author-highlights" xml:lang="en" view="all"><ce:section-title id="st0010">Highlights</ce:section-title><ce:abstract-sec id="as0010" view="all"><ce:simple-para id="sp0060" view="all"><ce:list id="l0005"><ce:list-item id="li0005"><ce:label>?</ce:label><ce:para id="p0005" view="all">Red gypsum can be used as a raw material for mineral carbonation.</ce:para></ce:list-item><ce:list-item id="li0010"><ce:label>?</ce:label><ce:para id="p0010" view="all">Carbonation efficiency of red gypsum attains maximum value at 75°C.</ce:para></ce:list-item><ce:list-item id="li0015"><ce:label>?</ce:label><ce:para id="p0015" view="all">High purity CaCO<ce:inf loc="post">3</ce:inf>(89.85–99.05%) is produced through pH swing process.</ce:para></ce:list-item><ce:list-item id="li0020"><ce:label>?</ce:label><ce:para id="p0020" view="all">Carbonation efficiency and CaCO<ce:inf loc="post">3</ce:inf>purity is higher with NH<ce:inf loc="post">4</ce:inf>HCO<ce:inf loc="post">3</ce:inf>rather than CO<ce:inf loc="post">2</ce:inf>.</ce:para></ce:list-item></ce:list></ce:simple-para></ce:abstract-sec></ce:abstract>]]>

CO2sequestrationCarbon capture and storageMineral carbonationCalcium carbonatepH swing

Amin Azdarpour、Mohammad Afkhami Karaei、Hossein Hamidi、Erfan Mohammadian、Maryam Barati、Bijan Honarvar

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Department of Petroleum Engineering, Marvdasht Branch, Islamic Azad University

School of Engineering, King's College, University of Aberdeen

Faculty of Chemical Engineering, Universiti Teknologi MARA

Department of Chemical Engineering, Shiraz Branch, Islamic Azad University

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2017

International Journal of Mineral Processing

International Journal of Mineral Processing

SCI
ISSN:0301-7516
年,卷(期):2017.169
  • 15
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