A new approach for the synthesis of N-beta-enaminocarbonyl 2-oxazolidinones through ring transformation reactions of uracil
Kitamura, Yoshiaki 1Ohshima, Yuto 1Nagaya, Yuki1
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作者信息
1. Gifu Univ
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Abstract
The reaction of N-1-sulfonyluracil derivatives bearing a 2-hydroxyethyl moiety at the 3-position with NaH under anhydrous conditions at room temperature affords the corresponding 2-oxazolidinone bearing the beta-enaminocarbonyl moiety. These products are useful diversifiable precursors toward various beta-amino acids and N-heterocyclic compounds. (C) 2021 Elsevier Ltd. All rights reserved.
NSTL
Elsevier