首页|SnSe nanocrystals decorated on carbon nanotubes for high-performance lithium-ion battery anodes

SnSe nanocrystals decorated on carbon nanotubes for high-performance lithium-ion battery anodes

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Tin selenide has been considered as one of the most promising anode materials for lithium-ion battery owing to its high theoretical capacity. In this work, a facile colloidal synthetic method was successfully used to obtain nanocomposites comprising ~7 nm SnSe nanocrystals and carbon nanotubes (SnSe NC/CNT). When applied as anode materials in lithium-ion battery, the SnSe NC/CNT nanocomposites exhibited excellent electrochemical performance with a reversible capacity of 706.5 mAh g?1 after 300 cycles at a constant current density of 200 mA g?1. The SnSe NC/CNT nanocomposites also delivered the high reversible capacity of 532.0 mAh g?1 at a high current density of 1.0 A g?1. The SnSe nanocomposites are advantageous to the ion and electron transport. Interconnected by CNT after annealing at 200 °C, SnSe NC/CNT nanocomposites can accommodate the volume expansion even after 300 cycles. The complex conversion and alloying reaction are studied by X-ray diffraction and X-ray absorption near edge structure.

Carbon nanotubesLithium-ion batteryNanocompositesoperando X-ray diffractionTin selenide

Jin A.、Um J.H.、Yu S.-H.、Chae S.I.、Park J.-H.、Kim S.-Y.、Lee S.、Chang H.、Kim J.H.、Hyeon T.、Sung Y.-E.

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Department of Chemical and Biological Engineering Korea University

Center for Nanoparticle Research Institute for Basic Science (IBS)

2022

Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
年,卷(期):2022.892
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