首页|Cp *Ir complex with mesobiliverdin ligand isolated from Thermoleptolyngbya sp. O-77
Cp *Ir complex with mesobiliverdin ligand isolated from Thermoleptolyngbya sp. O-77
扫码查看
点击上方二维码区域，可以放大扫码查看
原文链接
NSTL
Elsevier
We developed a new method to isolate a natural pigment of mesobiliverdin IX alpha (MBV) directly from phycocyanin of Thermoleptolyngbya sp. O-77 and synthesized a water-soluble Cp *Ir complex with the isolated MBV ligand. To obtain a high yield of MBV, we modified the conventional method by adding additional two steps: the protease digestion of phycocyanin by trypsin and the isolation of MBV by hydrophobic and silica gel column chromatographies. The Cp *Ir complex with MBV ligand was characterized by electrospray ionization-mass spectrometry, ultraviolet-visible-near-infrared absorption spectroscopy, Xray photoelectron spectroscopy, 1 H NMR spectroscopy, and H-H correlation spectroscopy. This is the first example of a platinum-group metal complex with MBV as a ligand. (c) 2022 Elsevier B.V. All rights reserved.
MesobiliverdinCp * Ir complexWater-solubleENERGY-TRANSFERRED ALGAPHYCOCYANOBILINCLEAVAGEREACTIVITYEXTRACTSPIGMENTSMODELS
NSTL
Elsevier
