首页|A facile green synthesis of porous hexagonal cobalt pyrovanadate electrode for supercapacitors by deep eutectic solvent

A facile green synthesis of porous hexagonal cobalt pyrovanadate electrode for supercapacitors by deep eutectic solvent

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Cobalt vanadate is a kind of promising electrode material for pseudo-supercapacitors because of their higher electrical conductivity, better electrochemical activity, and prominent specific capacitance than single metal oxides. In this paper, cobalt pyrovanadate (Co2V2O7) was primarily fabricated by a facile environment-friendly ionothermal method using a green deep eutectic solvent (DES) and followed the heat treatment in the air. The eutectic mixture discussed here was consisted of a hydrogen bond donor (urea) and acceptor (ChCl) in a 2:1 molar ratio. The as-prepared Co2V2O7 was porous hexagonal nanoplatelets, and its electrochemical performances were characterized by cycle voltammetry, galvanostatic charge/discharge and cycling stability tests in a three-electrode system with 2 M KOH electrolyte solution. The specific capacitance of the synthesized Co2V2O7 revealed 304 F g?1 at the current density of 1 A g?1. Surprisingly, it remained an excellent cycle performance with 103% in 100 charge/discharge cycles. Therefore, we have successfully presented a deep eutectic solvent derived routine to prepare porous hexagonal Co2V2O7 nanoplatelets electrode material.

Co2V2O7Deep eutectic solventPorous hexagonal nanoplateletsSupercapacitorsTransition metal vanadates

Yao G.、Zhang N.、Zhang Y.、Zhou T.

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Xi'an Northwest Geological Institute for Nonferrous Metals Co. Ltd.

2022

Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
年,卷(期):2022.892
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