首页|Bi@hollow carbon tube enabled high performance potassium metal batteries
Bi@hollow carbon tube enabled high performance potassium metal batteries
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NSTL
Elsevier
? 2022 Elsevier B.V.Potassium (K) metal batteries are attractive alternatives beyond lithium-ion batteries because of the large abundance, high theoretical specific capacity and low electrochemical potential of the K metal. However, K metal anode have been restrained by the uncontrollable K dendrite growth. A high-activity K metal anodes achieved by confining K metal into a Bismuth compound hollow carbon tube (Bi@CNT) freestanding matrix is reported. The homogeneous K ionic flux and reduced local current density during plating/stripping processes are enabled by the high electronic transport in the Bi@CNT matrix. Moreover, the “K-philic” Bi in the Bi@CNT can induce the nucleation of K metal and induce K to uniformly distribute in the electrode during cycling. Therefore, the obtained Bi@CNT composite K anode shows more excellent electrochemical performance in electroplating/stripping, greatly improves the stability (500 h at 0.5 mA cm?2 - 0.5 mA h cm?2and a low overpotential of 53 mV), and provides more choices for the development of potassium metal batteries. Furthermore, K@Bi@CNT||PTCDA full batteries exhibit excellent electrochemical performance with good rate capability and long cycling stability (103.3 mA h g?1 after 150 cycle at 0.1 A g?1).
Bi nanoparticlesCoaxial ElectrospinningHollow carbon tubePotassium metal batteries
Liu S.、Su Y.、Wang X.、Li X.、Shi J.、Huang M.、Shi Z.、Wang H.、Cheng G.
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School of Materials Science and Engineering Ocean University of China
NSTL
Elsevier
