Effect of the interlamellar anion on CuMgFe-LDH in solar photo-Fenton and Fenton-like degradation of the anticancer drug 5-fluorouracil

Costa-Serge, Nayara de M. ¹Goncalves, Rosembergue G. Lima ¹Ramirez-Ubillus, Manuel A. ¹Li, Chan ¹Hammer, Peter ²Chiron, Serge ¹Nogueira, Raquel F. Pupo

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作者信息

1. Sao Paulo State Univ UNESP
2. Univ Montpellier
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Abstract

The influence of the interlamellar anion in Layered Double Hydroxide was investigated for the first time in Fenton-like and solar photo-Fenton processes for the degradation of the anticancer drug 5-fluorouracil (5-FU). LDHs of the MgFeCu type were synthesized by coprecipitation with the insertion of CO32-, NO3- , SO42- and B(OH)4- . A strong effect of the interlamellar anion was observed on the catalytic activity with pseudo-first-order rate constant sequence (k): CuMgFe-B(OH)4 > CuMgFe-NO3 > CuMgFe-SO4 > CuMgFe-CO3. Using CuMgFe-B(OH)4, 5-FU was completely degraded under solar radiation after 20 min and after 40 min in the dark, with degradation efficiency maintained above 90% until the fourth cycle of use. It was found that molecular B-O and B-OH interactions induced modifications of the CuMgFe-B(OH)4 surface charge density, accelerating the reduction of Cu (II) and Fe(III), thus favoring reactive oxygen species generation. This performance denotes the excellent potential of CuMgFe-B(OH)4 for 5-FU degradation.

Key words

Hydrotalcite/Hydroperoxyl/superoxide radical/Singlet oxygen/Borate anion/LAYERED DOUBLE HYDROXIDES/HOSPITAL WASTE-WATER/HYDROGEN-PEROXIDE/OXIDATION/BORON/ACTIVATION/ADSORPTION/ZN/FLUOROURACIL/ENVIRONMENT

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出版年

2022

Applied Catalysis

ISSN：0926-3373

被引量10

参考文献量66

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