Defect engineering technique for the fabrication of LaCoO3 perovskite catalyst via urea treatment for total oxidation of propane

Feng, Chao ¹Gao, Qianqian ¹Xiong, Gaoyan ¹Chen, Yanfei ¹Pan, Yuan ¹Fei, Zhaoyang ²Li, Yanpeng ¹Lu, Yukun ¹Liu, Chenguang ¹Liu, Yunqi¹

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作者信息

1. China Univ Petr East China
2. Nanjing Technol Univ
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Abstract

The low defect content and poor oxygen mobility of perovskite catalysts limit its application in VOC elimination. Herein, we report a strategy involving defect engineering route following an easy urea treatment method to enhance the propane oxidation performance of perovskite catalysts. The constructed LaCoO3-D43 exhibits superior catalytic activity (T-90 = 309.3 degrees C), the T-90 value is 150 degrees C lower than that of LaCoO3, and excellent thermal stability against CO2 and H2O. Experimental results revealed that the urea pyrolysis resulted in the generation of La and O defects and rich surface-active Co species in high-valence states, increasing the utilization of Co active sites. DFT calculations show that the exposed Co surface is conducive to the adsorption and dissociation of oxygen and propane. This work provides a defect engineering strategy to effectively activate perovskite catalysts performance, and can be generalized for the fabrication of other types of perovskite catalysts.

Key words

Perovskite oxides/Defect engineering/Urea treatment/Propane oxidation/Oxygen species activation/MOLECULAR-OXYGEN/OXIDES/CO/TEMPERATURE/FACILE/MN/COMBUSTION/ACTIVATION/REMOVAL/CU

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出版年

2022

Applied Catalysis

ISSN：0926-3373

被引量49

参考文献量49

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