Journal of Alloys and Compounds2022,Vol.8939.DOI:10.1016/j.jallcom.2021.162340

Facile Synthesis of Bimetal Nickel Cobalt Phosphate Nanostructures for High-Performance Hybrid Supercapacitors

Li, Min Luo, Yunyun Jia, Chen Zhang, Qiankun Luo, Guoxi Zhao, Libo Boukherroub, Rabah Jiang, Zhuangde
Journal of Alloys and Compounds2022,Vol.8939.DOI:10.1016/j.jallcom.2021.162340

Facile Synthesis of Bimetal Nickel Cobalt Phosphate Nanostructures for High-Performance Hybrid Supercapacitors

Li, Min 1Luo, Yunyun 1Jia, Chen 1Zhang, Qiankun 1Luo, Guoxi 1Zhao, Libo 1Boukherroub, Rabah 2Jiang, Zhuangde1
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作者信息

  • 1. Xi An Jiao Tong Univ
  • 2. Univ Lille
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Abstract

Herein, bimetal nickel-cobalt phosphate (NiCoP) nanostructures coated on nickel foam (NF) were synthesized for hybrid supercapacitors by a facile one-step potentiostatic electrodeposition method. The optimization of the capacitive performance for supercapacitors was achieved by varying the deposition time from 5 to 20 min. When the electrodeposition time was 15 min, an optimal performance with the NiCoP/NF2 was achieved. A specific capacity of 883 C.g(-1) was recorded at a current density of 1 A.g(-1), a best rate performance of 87% along with a highest coulombic efficiency of 100%, revealing good capacitive performance and excellent reversibility. Furthermore, NiCoP/NF-2 was assessed as a positive electrode in a hybrid supercapacitor. Using activated carbon (AC) as a negative electrode, the assembled device exhibited an energy density of 54 Wh.kg(-1) at a power density of 2.7 kW.kg(-1) with a large working potential window of 0-1.8 V. After charging to 3.6 V for 19 s, two hybrid supercapacitor devices connected in series could light up a red LED for 191 s, which indicates that the proposed electrodeposition synthesis process and the prepared NiCoP composites hold high potential for applications in the field of energy storage technology. (C) 2021 Elsevier B.V. All rights reserved.

Key words

Nickel cobalt phosphates/Nickel foam/Electrodeposition/Energy storage/Supercapacitors/HIGH-ENERGY/ASYMMETRIC SUPERCAPACITOR/ELECTRODE/FOAM/DENSITY/NANOCOMPOSITES/NANOPARTICLES/HYDROXIDES/MORPHOLOGY/NANOSHEETS

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出版年

2022
Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
被引量34
参考文献量42
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