首页|(162758)Crystal structure, luminescence properties and thermal stability of Lu~(3+) ion-substituted BaY_2Si_3O_(10): Dy~(3+) phosphors
(162758)Crystal structure, luminescence properties and thermal stability of Lu~(3+) ion-substituted BaY_2Si_3O_(10): Dy~(3+) phosphors
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NSTL
Elsevier
A series of Dy~(3+) activated Ba(YLu)_2Si_3010 samples were prepared by high temperature solid-phase method. The purity of the phase was determined and the structural changes were analyzed. Under excitation at 350 nm, the BaY_2Si_3O_(_10): Dy~(3+) phosphor shows two stronger luminescence peaks at 486 nm and 572 nm and weaker emission peak at 668 nm. In addition, with the continuous replacement of Y~(3+) in the matrix by Lu~(3+) ions, the chromaticity coordinates of samples in the system can be adjusted from the cold white region to the warm white region, and the luminescence performance of phosphors can be effectively improved. It was observed that the thermal stability of the phosphor was gradually enhanced with Lu~(3+) concentration increases, and the emission intensity of the BaLu_2Si_3O_(10): 0.04Dy~(3+) phosphor at 453 K could still maintain 83.78% of that at room temperature, which was discussed in conjunction with the Debye temperature and the rigid structure model to provide a reference for the improvement of the thermal stability performance. In addition, the increase of the concentration of Lu~(3+) ions doping will shorten the lifetime of phosphors due to the non-radiative energy transfer caused by the shortening of the ion distance in the lattice.
NSTL
Elsevier
