首页|The first shell structure of He environment in tetracene-(He)N clusters manifested in REMPI spectra

The first shell structure of He environment in tetracene-(He)N clusters manifested in REMPI spectra

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The satellite lines belonging to the clusters of tetracene Tc with He are revealed in REMPI spectra of Tc seeded in the supersonic expansion of He. These well-resolved peaks are shifted to the red by 35.7(9) cm(-1) relative to the lines of bare Tc. The data by Even et al. (J. Chem. Phys.115, 2069 (2001)) on the shift of absorption lines for clusters Tc-(He) N allow us to assign this peak to Tc-(He)8 cluster. This result confirms one of the earlier suggested structures of the first layer of He atoms surrounding tetracene in the He nanodroplet.

TetraceneHelium environmentSolvation shellClustersHe nanodropletINDUCED FLUORESCENCE SPECTROSCOPYDER-WAALS COMPLEXESMOLECULESANTHRACENEENERGETICSPENTACENEDYNAMICSSTATESNEAR

Bogomolov, Alexandr S.、Rogoveshko, Vladislav M.、Baklanov, Alexey, V

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Voevodsky Inst Chem Kinet & Combust

2022

Chemical Physics Letters

Chemical Physics Letters

EISCI
ISSN:0009-2614
年,卷(期):2022.787
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