首页|Isomerization of (Z)-asarone to (E)-asarone from Piper marginatum leaves by the Quadrus u-lucida larvae

Isomerization of (Z)-asarone to (E)-asarone from Piper marginatum leaves by the Quadrus u-lucida larvae

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? 2022Despite being rich in phenylpropanoids with insecticidal activity, Piper marginatum leaves are frequently attacked by the larvae of the Quadrus u-lucida moth. GC/MS analysis indicated isomerization of phenylpropanoid (Z)-asarone to (E)-asarone from the leaves by larvae. The phenylpropanoids (Z)-asarone, dillapiole and (E)-asarone were identified in concentrations of 48.01, 24.02 and 36.07 μg/mg, respectively. Only the phenylpropanoid (E)-asarone was found in the larval tissues and regurgitant material in a concentration of 15.52 and 2.53 μg/mg, respectively. Since (Z)-asarone has been reported to be more toxic than (E)-asarone, the isomerization of (Z)-asarone may be associated with the detoxification mechanism of larvae.

AsaroneBiotransformationPhenylpropanoidPiperaceaeRegurgitation

Fontes Silva M.F.、Ramos C.S.、da Silva R.R.

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Department of Chemistry Rural Federal University of Pernambuco

2022

Phytochemistry Letters

Phytochemistry Letters

SCI
ISSN:1874-3900
年,卷(期):2022.47
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