Nature of Griffiths phase and ferromagnetic 3d-4f interaction in double-perovskite Dy2CoMnO6
Zhou, Shiming 1Hou, Li 1Yang, Liping 1Yuan, Xueyou 1Xin, Yang 1Shi, Lei 1Zhao, Jiyin1
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作者信息
1. Univ Sci & Technol China
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Abstract
Double perovskites Dy2CoMnO6 (DCMO) was synthesized by a sol-gel method and the structure and magnetic properties were systematically investigated. Both X-ray diffraction and Raman spectrum indicate that double pervoskite DCMO has a monoclinic structure with a space group P21/n. A Griffiths phase is confirmed to be existing in DCMO by the magnetic behaviors, which is significantly different from the behaviors of the non-Griffiths phase of Gd2CoMnO6 (GCMO) recently reported in reference. It is suggested that the origins of the different short-range magnetic orders of them can be attributed to the different 3d-4f exchange interactions in DCMO and GCMO, besides the effect of the unavoidable anti-site disorder, inter-rupting the long-range ferromagnetic (FM) order of Co2+-O-Mn4+, resulting in the formation of short-range FM order. The effects of A-site rare-earth Re3+ ions on the magnetism of double perovskite Re2Co(Ni)MnO6 are dominated by the combining and competing functions of the radius and the moments of rare earth ions (or the 3d-4f exchange interactions). The FM/AFM coupling is not only related to the most outer 4f electrons of the rare earth ions, but also to the inner 5d/6s orbital electrons. (C) 2021 Elsevier B.V. All rights reserved.
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Elsevier