Abstract
The East Bokaro Basin of the Damodar valley is a potentially prospective CBM(coalbed methane)play having significant cumulative coal seam thickness,in-situ gas content,vitrinite percentage,and adequate thermal maturity.Successful CBM recovery needs a detailed understanding of the organic content,pore structures/networks,storage properties and gas flow mechanism.The present work attempts to systematically investigate East Bokaro coal for organo-petrographic controls on gas content and generation,variations in sorption capacity and saturation,pore mechanisms,cleat intensity,cleat aperture distribution and spacing.The values of in-situ gas,sorption capacity and methane concentration(C1)vary from 3.52 to 30.93 cc/g(dry ash-free basis),15.40-32.40 cc/g(dry ash-free basis),and 66-93 vol%,respectively.The atomic ratios H/C and O/C indicate that thermally matured coal seams contain type III-IV kerogen positioned in the dry gas window.The decrease of hydrogen-containing liptinite with increasing depth reveals the function of thermal gradient on the cracking of liptinitic compounds with successive evolution of hydrocarbons and the development of a carbon-rich pore matrix.The H/C ratio is also influenced by the increasing content of vitrinite and reflectance values of deeper coal.More than 63 % of desorbed gas was determined from desorption measurement and low sorption time(τ,mainly<10 days).This demonstrates good diffusion characteristics of the studied coal.It shows the tendency of desorbed gas diffusion from pores reaches to cleat-fractures with negligible influence of secondary mineral infillings.The high-pressure sorption studies of methane on various samples indicate substantial open-pore characteristics,supporting adsorption,diffusion and gas release.The relationship of C3/C1 and C2/C1 ratios demonstrates that the hydrocarbons in coal primarily originated from the thermogenic transformation of organic matter.Such an assessment is also supported by the stable isotope(8~(13)C1)value that ranges between-22.70 %o and-57.30 ‰.However,some of the lighter isotope values(<-50 ‰)indicate a mixed origin of gases,which may be due to the influx of fresh-water to coal associated aquifers carrying bacteria received from local drainage.Geochemically and thermally altered dissolved and partially filled pores,shown by SEM photographs,negligibly influence gas sorption,diffusion,and flow mechanism in coalbeds.The pore network model signifying that the studied coal seams are microstructurally different comprises a lateral difference in pore and cleat/fracture.
NSTL