首页|Gas-liquid microextraction coupled with magnetic-assisted dispersive solid-phase extraction clean-up for multi-residue pesticide analysis in fatty foods of animal origin

Gas-liquid microextraction coupled with magnetic-assisted dispersive solid-phase extraction clean-up for multi-residue pesticide analysis in fatty foods of animal origin

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  • NSTL
  • Elsevier
An effective sequential clean-up method by coupling gas-liquid microextraction (GLME) and magnetic-assisted dispersive solid phase extraction (d-SPE) termed as GLME-MA-d-SPE has been developed for multi-residue pesticide analysis in different fatty foods of animal origin. GLME is applied as a primary clean-up step to remove low-volatile interferences, followed by a secondary clean-up technique through adsorptive removal using d-SPE to eliminate other co-extracts like organic acids in fatty biological samples. As much as 99.3% of lipid substances were effectively eliminated by this powerful clean-up method, and the chromatographic analysis by GC-MS showed at least two orders of magnitude reduction for peaks of interference. Analytical results verified the accuracy and precision of this method with recoveries of 50 pesticides ranged from 60.5% to 119.7%, and RSDs of less than 20%. Permethrin was present in salmon, pork and egg samples, but the concentrations were within the maximum residue levels (MRLs) permitted by both national and international regulations. The GLMEMA-d-SPE technique minimizes matrix effects, and it exhibits significant potential as an analytical technique of food safety control systems for broad-spectrum screening trace-level environmental pollutants in complex biological matrices.

Gas-liquid microextractionDispersive solid phase extractionMulti-residue pesticides analysisClean-upFatty food of animal origin

Kaw, Han Yeong、Jin, Xiangzi、Liu, Yunan、Cai, Long、Zhao, Xiangai、Wang, Juan、Zhou, John L.、He, Miao、Li, Donghao

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Yanbian Univ, Dept Chem, Pk Rd 977, Yanji 133002, Jilin, Peoples R China

Minist Nat Resources, Key Lab Marine Ecosyst & Biogeochem, State Ocean Adm, Baochubei Rd 36, Hangzhou 310012, Peoples R China

Yanbian Univ, Coll Agr, Pk Rd 977, Yanji 133002, Jilin, Peoples R China

Univ Technol Sydney, Ctr Green Technol, Sch Civil & Environm Engn, 15 Broadway, Sydney, NSW 2007, Australia

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2021

10.1016/j.lwt.2020.110448

LWT-Food Science & Technology

LWT-Food Science & Technology

ISSN：0023-6438
年,卷(期)：2021.137
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