首页|Environmental-friendly lead-free chiral Mn-based metal halides with efficient circularly polarized photoluminescence at room temperature
Environmental-friendly lead-free chiral Mn-based metal halides with efficient circularly polarized photoluminescence at room temperature
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NSTL
Elsevier
? 2022 Elsevier B.V.In recent years, chiral organic-inorganic hybrid metal halides have attracted more and more attention from researchers. However, most chiral metal halides are based on toxic Pb elements. In this work, we first successfully prepared a pair of lead-free manganese-based metal halide enantiomers (R/S-1-PPA)2MnBr4 (R/S-1-PPA=R/S-1-Phenylpropan-1-amine). Under the excitation of 365 nm UV light, (R/S-1-PPA)2MnBr4 exhibited bright green emission, which can be attributed to the spin-forbidden d-d transition of Mn2+. In addition, the decay lifetimes were as high as 32.57 μs and 33.60 μs for (R-1-PPA)2MnBr4 and (S-1-PPA)2MnBr4, respectively. (R/S-1-PPA)2MnBr4 showed notable circular dichroism (CD) signals and displayed highly efficient circularly polarized photoluminescence (CPPL) at room temperature with the large glum of ? 0.01 and 0.008, respectively. The high glum enables them to be a series of very promising materials for the development of chiral optoelectronic devices based on chiral hybrid metal halides. Finally, the white LED device constructed with (R-1-PPA)2MnBr4 also showed a wide color gamut, as high as 107% of NTSC, and a “warm” white light-correlated color temperature of 6883 K, which indicated it has good competitiveness in the application of white light LED devices.
ChiralCPPLLead-freeManganeseMetal halides
Wang B.、Wang C.、Chu Y.、Zhang H.、Sun M.、Wang H.、Wang S.、Zhao G.
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Tianjin Key Laboratory of Molecular Optoelectronic Sciences Department of Chemistry National Demonstration Center for Experimental Chemistry & Chemical engineering Education School of Science Tianjin University
NSTL
Elsevier
