Oligolayered Co@MXene with a Co center dot center dot center dot SO3 cation-pi bridge for ultra-rapid catalytic oxidation of a novel "forever chemical" OBS
Yu, Gang Li, Shangyi Gu, Mengbin Huang, Jun Wang, Yujue
Oligolayered Co@MXene with a Co center dot center dot center dot SO3 cation-pi bridge for ultra-rapid catalytic oxidation of a novel "forever chemical" OBS
Yu, Gang 1Li, Shangyi 1Gu, Mengbin 1Huang, Jun 1Wang, Yujue1
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作者信息
1. Tsinghua Univ
折叠
Abstract
Sodium p-perfluorous nonenoxybenzene sulfonate (OBS) as a novel alternative to perfluorooctane sulfonate (PFOS), belongs to the family of per- and polyfluoroalkyl substances (PFASs). We demonstrated that Co-based oligolayered MXene (Co@o-MXene) achieved the complete oxidation of OBS during catalytic ozonation with peroxymonosulfate (PMS). The optimized catalyst exhibited 78.5% OBS oxidation in only 2 min, and the oxidation route was thoroughly investigated by Fukui function calculations and QTOF-MS/MS analysis. However, within the fluoroprotein (FP) foam solution, high TOC removal was performed via the newly designed two-stage ozonation process. Systematic studies indicated that OBS can donate electrons through a Co center dot center dot center dot SO3 cation-pi bridge on the surface of o-MXene/PMS accompanied by the generation of reactive oxygen species (ROS), the strong adsorption energy (Eads) value of PMS, enhanced total density of states (TDOS) and uneven electron density in this reaction system. This work extended the potential of newly developed MXene family materials to decompose PFAS.
Key words
Foamless ozonation/OBS/Co@o-MXene/PMS activation/Co center dot center dot center dot SO3 cation-pi/SUBSTANCES PFASS/RATE CONSTANTS/BISPHENOL-A/PEROXYMONOSULFATE/RADICALS/DEGRADATION/PERFORMANCE/ACTIVATION/CARBONATE/OZONATION
NSTL
Elsevier