首页|(162959)Rational design of CuO/In_2O_3 heterostructures with flower-like structures for low temperature detection of formaldehyde

(162959)Rational design of CuO/In_2O_3 heterostructures with flower-like structures for low temperature detection of formaldehyde

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Rational design of metal oxide heterostructures is of great importance for gas sensors to be applicable in the detection of inflammable, explosive and toxic gases. Herein, we designed CuO/In_2O_3 heterostructures with flower-like structures via a highly efficient one-step hydrothermal technique and constructed optimal structures to improve formaldehyde sensing properties. Consequently, the obtained 7-CuO/In_2O_3 flowerlike structures with uniform p-n heterostructure and a large quantity of oxygen vacancies exhibits the best sensing properties for detecting formaldehyde. The corresponding response value is 11.67-10 ppm formaldehyde at a low operating temperature of 100 °C, which is approximately 2.97 times higher than that of pure ln_2O_3 sensor (3.93 at 200 °C). Besides, the 7-CuO/In_2O_3 sensor also exhibits good reproducibility and stability, sub-ppm-level detection limit (1.38-0.5 ppm), high selectivity, and outstanding long-term stability, which benefits from the synergistic effect of strong oxygen adsorption capacity, p-n heterojunction between CuO and ln_2O_3, catalytic effect of CuO, and the unique flower-like structures, showing the great potential for practical formaldehyde detection.

CuO/In_2O_3Flower-like structuresOxygen vacancyP-n heterojunctionGas sensor

Dan Meng、Tongtong Qiao、Guosheng Wang

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College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China

2022

Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
年,卷(期):2022.896
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