首页|Construction of g-C3N4/Au/NH2-UiO-66 Z-scheme heterojunction for label-free photoelectrochemical recognition of D-penicillamine
Construction of g-C3N4/Au/NH2-UiO-66 Z-scheme heterojunction for label-free photoelectrochemical recognition of D-penicillamine
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NSTL
Elsevier
The wide clinical application of D-penicillamine (D-PA) makes it inevitably accumulates in the environment, seriously threatening human health and the ecological environment. To better supervisory control D-PA, a highly sensitive and reliable photoelectrochemical (PEC) sensor based on gold nanoparticles (Au NPs) loaded on graphitic carbon nitride sheet and hexagonal NH2-UiO-66 composite (g-C3N4/Au/NH2-UiO-66 ) was synthesized. Tactfully using the strong bonding between D-PA and Au NPs and the effective carrier separation of Z-scheme heterojunction, the designed g-C3N4/Au/NH2-UiO-66 PEC sensor without an extra recognition unit exhibited a selective and sensitive photocurrent to D-PA. With the aid of UV diffuse reflectance spectra (UV-DRs), electron paramagnetic resonance (EPR) characterization, and free radical capture experiments, the electron transfer path of the PEC sensing system was deduced. The proposed g-C3N4/Au/NH2-UiO-66 PEC-based sensor achieved a low detection limit of 0.0046 mu M (S/N = 3) with a wide linear response ranging from 10 nM to 400 mu M. In addition, its good stability and selectivity also laid a good foundation for practical applications.
D -penicillaminePhotoelectrochemical sensorZ-Scheme heterojunctiong-C3N4/Au/NH2-UiO-66ELECTRON MEDIATORHETEROSTRUCTURESPHOTOCATALYSTNANOPARTICLESCOMPOSITESUIO-66-NH2ENHANCE
NSTL
Elsevier
