首页|Emerging near-unity internal quantum efficiency and color purity from red-emitting phosphors for warm white LED with enhanced color rendition

Emerging near-unity internal quantum efficiency and color purity from red-emitting phosphors for warm white LED with enhanced color rendition

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A robust and bright red emitter is recognized as a key enabler for high-quality warm white light-emitting diode (w-LED). Herein, triple molybdate scheelite-type NaCaLa1-x(MoO4)3:xEu3+ (NCLM:xEu3+) phosphors derived from NaCaLa(MoO4)3 host by the equivalent-valent substitution strategy are successfully synthesized and systematically studied. Impressively, the NCLM:Eu3+ phosphors (λem = 615 nm) can be effectively stimulated by 395 and 466 nm light, exhibiting an ultra-high color purity and quantum efficiency close to 100%. The structure-related emission characteristics were analyzed based on the Judd-Oflet theory. The packaged white LED device used tri-color phosphors displays a superior color rendering index of 86.0 and low correlated color temperature of 2797 K. Moreover, the NCLM-based polydimethylsiloxane film maintains an impressive luminescent performance when it is folded or bent, demonstrating the potential applications in the field of flexible display and other light-emitting devices.

Energy transferFlexible applicationlight-emitting diodePhosphorsPlant lighting

Sun L.、Wang B.、Yang S.、Liu Y.

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MOE Key Laboratory for Non-equilibrium Synthesis and Modulation of Condensed Matter State Key Laboratory for Mechanical Behavior of Materials School of Physics Xi'an Jiaotong University

College of Chemistry and Chemical Engineering Key Laboratory of Advanced Ceramic Materials and Devices Inner Mongolia University of Science and Technology

2022

Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
年,卷(期):2022.899
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