首页|Electrochemical Ce(III)/Ce(IV) interconversion, electrodeposition, and catalytic CO <-> CO2 interconversion over terpyridine-modified indium tin oxide electrodes

Electrochemical Ce(III)/Ce(IV) interconversion, electrodeposition, and catalytic CO <-> CO2 interconversion over terpyridine-modified indium tin oxide electrodes

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  • NSTL
  • Elsevier
Indium tin oxide (ITO) has extensively used as an electrode in diverse application areas of electrochemistry, displays, photovoltaics, and catalysts. Herein, terpyridine-modified ITO and thioterpyridinefunctionalized Au-modified ITO electrodes were prepared and evaluated for electrochemical redox behaviors and conversion rates of Ce(III)/Ce(IV) ions, and recycling recovery rates on the newly developed electrode by cyclic voltammetry and amperometry. Scanning electron microscopy, X-ray photoelectron spectroscopy, Ultraviolet photoelectron spectroscopy, X-ray diffraction crystallography, and fluorescence spectroscopy were employed for the physiochemical properties of the demonstrated electrodes before and after electrochemistry. The interfacial energy level was examined by ultraviolet photoelectron spectroscopy for ITO-Au and ITO-Au-STpy. Density functional theory calculations were performed to examine complexation between the functionalized ligand and Ce(III)/Ce(IV) ions by obtaining molecular orbital energy levels and thermodynamics. Thermal CO oxidation catalytic activity was tested for Ceelectrodeposited ITO electrode. In addition, electrochemical CO2 reduction performance was evaluated for Au-modified ITO electrode with and without thioterpyridine-functionalization. (C) 2021 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

Ce(IIIIV) ionTerpyridine-functionalizationElectrodepositionDensity functional theoryInterfacial energy levelCO/CO2 catalytic interconversionCE3+/CE4+ REDOX COUPLELANTHANIDE COMPLEXESOXYGEN VACANCIESNITRIC-ACIDREDUCTIONOXIDATIONMORPHOLOGYAUPERFORMANCE

Park, So Jeong、Maeng, Ju Young、Joo, Min Hee、Kang, Jun-Gill、Rhee, Choong Kyun、Sohn, Youngku

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Chungnam Natl Univ

2022

10.1016/j.jiec.2021.11.029

Journal of industrial and engineering chemistry

Journal of industrial and engineering chemistry

EISCI
ISSN：1226-086X
年,卷(期)：2022.106
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