Journal of Alloys and Compounds2022，Vol.91610.DOI:10.1016/j.jallcom.2022.165482

Effect of Co-Fe alloy nanoparticles on the surface electronic structure of molybdenum disulfide nanosheets and its application as a bifunctional catalyst for rechargeable zinc air battery

Shang, Xiaonan Shen, Qiujie Xiong, Yi Jiang, Zhongqing Qin, Chu Tian, Xiaoning Yang, Xufeng Jiang, Zhong-Jie
Journal of Alloys and Compounds2022，Vol.91610.DOI:10.1016/j.jallcom.2022.165482
✕
  • NSTL
  • Elsevier

Effect of Co-Fe alloy nanoparticles on the surface electronic structure of molybdenum disulfide nanosheets and its application as a bifunctional catalyst for rechargeable zinc air battery

Shang, Xiaonan 1Shen, Qiujie 1Xiong, Yi 1Jiang, Zhongqing 1Qin, Chu 1Tian, Xiaoning 1Yang, Xufeng 2Jiang, Zhong-Jie3
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作者信息

  • 1. Zhejiang Sci Tech Univ
  • 2. Fire Brigade Junct Binhai Two Rd & Xingci Four Rd,, Ningbo 315336, Zhejiang, Peoples R China
  • 3. South China Univ Technol
  • 折叠

Abstract

It is of great significance to improve the performance of electrocatalysts by constructing suitable heterogeneous interfaces to adjust the electronic structure of their surfaces. Here, we design and synthesize Co-Fe alloy nanoparticles (NPs) modified nitrogen-doped cubic carbon box (NC) supported MoS2 nanosheets (NC@ MoS2@Co-Fe) as a bi-functional electrocatalytic electrode material, which possesses excellent electrocatalytic oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) performance. The NC@ MoS2@Co-Fe exhibits remarkable bifunctional electrocatalytic activities with an ORR half-wave potential of 0.73 V in 0.1 M KOH electrolyte and an OER overpotential of 400 mV, driving a current density of 10 mA cm-2. The advanced catalytic performance can be attributed to the unique heterojunction structure of the catalyst. The size of the Co-Fe alloy NPs supported on MoS2 can be tuned to avoid the excessive growth of alloy NPs and to expose more catalytic active sites. Meanwhile, the loaded Co-Fe alloy NPs should be covered with a calcined carbon layer derived from the organic ligand to prevent oxidation passivation and particle aggregation. The structure formed by Co-Fe alloy NPs and NC@MoS2 optimizes the electronic structure of the active center and accelerates the electrocatalytic reaction rate, thus synergistically improving the bi-functional electrocatalytic activity of the NC@MoS2@Co-Fe catalyst and can be applied to rechargeable zinc air batteries.

Key words

Co-Fe alloy/Molybdenum disulfide nanosheets/Surface electronic structure/Bifunctional catalyst/Rechargeable zinc air battery/OXYGEN REDUCTION/CARBON NANOTUBES/MOS2 NANOSHEETS/EFFICIENT/ELECTROCATALYST/NITROGEN/NANOFIBERS/GRAPHENE

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出版年

2022
Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN：0925-8388
被引量6
参考文献量43
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