首页|Building a two-dimensional network from mixed-valence copper units held together by acetone bridges
Building a two-dimensional network from mixed-valence copper units held together by acetone bridges
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NSTL
Wiley
The mixed-valence supramolecular product di-μ2-acetone-di- μ3-trifluoroacetato-deca-μ2-trifluoroacetato- octacopper(I)dicopper(II), [Cu10(C2F3O 2)12(C3H6O)2] or {[CuI 4(O2CCF3)4] 2-{μ2-OC(CH3)2} 2-[CuII 2(O2CCF3) 4]}, was prepared by co-deposition of two building units, namely a bis-acetone adduct of [CuII 2(O2CCF 3)4] and a very electrophilic tetranuclear [Cu I 4(O2CCF3)4] complex. The asymmetric unit contains one molecule of the compound with a total of ten independent Cu atoms. Acetone molecules serve as bridges between the [Cu II 2(O2CCF3)4] and [CuI 4(O2CCF3)4] units. Additionally, the tetracopper(I) trifluoroacetate units are involved in intermolecular Cu...O interactions, forming a layered two-dimensional network in the extended structure.
NSTL
Wiley
