首页|Multiple charging and chemical stability of tripodal catholyte redoxmers

Multiple charging and chemical stability of tripodal catholyte redoxmers

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  • NSTL
  • Elsevier
Macromolecular catholyte materials store multiple positive charges in all-organic redox flow cells. Presently, little is known about the electronic structure and chemical stability of these macromolecules in different states of charge. Here we demonstrate that in propeller-like catholyte trimers (tripods), chemical stability increases when they become fully charged.

Radical ionsElectron spin resonanceElectrochemistryFlow batteryKineticsELECTROCHEMICAL ENERGY-STORAGEFLOW BATTERIESELECTRON-TRANSFEROVERCHARGE PROTECTIONDIRADICAL DICATIONTRANSPORTCROSSOVERPOLYMERSDESIGNSTATE

Shkrob, Ilya A.、Robertson, Lily A.、Zhang, Lu、Zhang, Jingjing

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Argonne Natl Lab

2022

10.1016/j.cplett.2021.139212

Chemical Physics Letters

Chemical Physics Letters

EISCI
ISSN：0009-2614
年,卷(期)：2022.787
  • 38