首页|Heat capacity of flexible MOFs M2(bdc)2(dabco)(M = Co,Ni,Cu,Zn)

Heat capacity of flexible MOFs M2(bdc)2(dabco)(M = Co,Ni,Cu,Zn)

扫码查看
原文链接
  • NSTL
The temperature behavior of the heat capacity of isostructural compounds M2(bdc)2(dabco)(M = Co,Ni,Cu,Zn)is analyzed.It is shown that all the samples are characterized by phase transitions at 12K and 60K.The phase transition observed in the Zn complex at-130K is not manifested in M2(bdc)2(dabco)(M = Co,Ni,Cu)because of the spin-phonon interaction between paramagnetic M~(2+)ions and the mobility of frameworks of these compounds.

Metal-organic frameworksHeat capacityPhase transitionsSpin-phonon interaction

Denis P.Pishchur、Nikolay B.Kompankov、Svetlana G.Kozlova

展开 >

Nikolaev Institute of Inorganic Chemistry,Siberian Branch,Russian Academy of Sciences,Lavrentyev Av.,3,RU,630090,Novosibirsk,Russian Federation

2022

10.1016/j.micromeso.2022.112093

Microporous and mesoporous materials

Microporous and mesoporous materials

EISCI
ISSN：1387-1811
年,卷(期)：2022.341
  • 1
  • 46