首页|In situ fabrication of highly porous foam-like Zn nanostructures on gas diffusion layer for selective electrocatalytic reduction of carbon dioxide to carbon monoxide
In situ fabrication of highly porous foam-like Zn nanostructures on gas diffusion layer for selective electrocatalytic reduction of carbon dioxide to carbon monoxide
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Electrochemical reduction of CO2 is regarded as a promising technique for converting unwanted CO2 into high-value chemicals. Among the various electrocatalysts that are crucial for overcoming sluggish reduction processes, Zn has been continuously studied because of its suitable catalytic activity and abundance in the earth's crust. In this study, we fabricated highly porous foam-like Zn nanostructures on a gas diffusion layer (GDL) using hydrothermal growth and in situ reduction process. The prepared electrode showed a CO partial current density of 20.9 mA-cmr2 at-1.10 V, which is approximately 10 times higher than that of the bare Zn foil. Moreover, the fabricated electrode can be directly applied to the large-scale flow cell system without further modification. The flow cell system with the fabricated electrode showed a current density of approximately 200 mA-cm~(-2) and CO faradaic efficiency of 75% on a 2 h long experiment at 2.7 V cell voltage, which clearly confirms the possibility of highly porous Zn nanostructures on GDL.
CO2 reductionElectrocatalysisElectrochemistryZincNanorod
Juwon Jeong、Jiwoo Choi、Segeun Jang
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Center for Nanoparticle Research, Institute for Basic Science (IBS), Seoul National University, Seoul 08826, Republic of Korea
Clobal Frontier Center for Multiscale Energy Systems, Seoul National University, Seoul 08826, Republic of Korea
School of Mechanical Engineering, Kookmin University, Seoul 02707, Republic of Korea
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