首页|High yield 1-L scale synthesis of ZIF-8 via a sonochemical route

High yield 1-L scale synthesis of ZIF-8 via a sonochemical route

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ZIF-8 was prepared using a sonochemical method under pH-adjusted synthesis conditions using NaOH (aq) with a minimal amount of triethylamine. After optimizing the synthesis parameters, it was extended successfully to 1 L-scale synthesis with an 85% product yield at a high substrate concentration (Zn~(2+):-DMF = 1:9.3) in 2 h without compromising the textural properties. The prepared ZIF-8 samples after pel-letization demonstrating excellent catalytic activity in the Knoevenagel condensation reaction of benzaldehyde with malononitrile.

ZIF-8Sonochemical synthesispH controlZIF-8 pelletsKnoevenagel condensation reaction

Hye-Young Cho、Jun Kim、Se-Na Kim

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Department of Chemical Engineering, Inha University, Incheon 402-751, Republic of Korea

2013

Microporous and mesoporous materials

Microporous and mesoporous materials

EIISTP
ISSN:1387-1811
年,卷(期):2013.
  • 134
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