首页|Sandwich-like porous MXene/Ni3S4/CuS derived from MOFs as superior supercapacitor electrode
Sandwich-like porous MXene/Ni3S4/CuS derived from MOFs as superior supercapacitor electrode
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NSTL
Elsevier
? 2022Metal-organic frameworks (MOFs) have ordered porous structure and intriguing properties for supercapacitors, however, poor conductivity and cycle stability limits their application. To solve these problems, hence, a simple strategy is proposed, by which MOFs are in-situ grown in the porous conductive p-MXene substrate. And then, along with the introduction of CuS, the grown Ni-MOF is derived to Ni3S4, which is more stable and more electrochemically active. Due to higher contact area, excellent synergistic effect and more exposed active sites, the prepared sandwiched p-MXene@Ni3S4/CuS nanostructure displays a big specific capacitance (1917 F·g?1) and superior cycling performance (91.2%@30000). What's more, the assembled p-MXene@Ni3S4/CuS//AC asymmetric device delivers a high energy density of 87.62 Wh·Kg?1 at the power density of 775.02 W·Kg?1, suggesting that this material provides a brilliant candidate for energy storage.
CuSMXeneNi-MOFPseudocapacitanceSulfurization
Guo H.、Yang F.、Zhang J.、Zhang T.、Hao Y.、Yang W.、Wang M.
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Key Lab of Eco-Environments Related Polymer Materials of MOE Key Lab of Bioelectrochemistry and Environmental Analysis of Gansu Province College of Chemistry and Chemical Engineering Northwest Normal University Gansu International Scientific and Technolog